psychological and social problems
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Question
If she marries him, his first wife will leave him
Answer
Praise be to Allah.The issue of marriage is a personal matter which concerns you alone. You are not responsible for whatever happens between him and his first wife.
If you have several options, then choose that which is the best. But if you only have the choice between marrying him and remaining single, then I think that marrying him is better.
Source: IslamQA (Sheikh Muhammed Salih Al-Munajjid)